What does kulinkovich reaction mean?

Definitions for kulinkovich reaction
kulinkovich re·ac·tion

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Wiktionary

  1. Kulinkovich reactionnoun

    The organic synthesis of cyclopropanols via reaction of esters with dialkyldialkoxytitanium reagents, generated in situ from Grignard reagents bearing hydrogen in beta-position and titanium(IV) alkoxides such as titanium isopropoxide.

Wikidata

  1. Kulinkovich reaction

    The Kulinkovich reaction describes the organic synthesis of cyclopropanols via reaction of esters with dialkyldialkoxytitanium reagents, generated in situ from Grignard reagents bearing hydrogen in beta-position and titanium alkoxides such as titanium isopropoxide. This reaction was discovered by Kulinkovich and coworkers in 1989. The titanium reagent can be used catalytically. Titanium catalysts are ClTi(OiPr)3 or Ti(OiPr)4, ClTi(OtBu)3 or Ti(OtBu)4, Grignard reagents are EtMgX, PrMgX or BuMgX. Solvents can be Et2O, THF, Toluol. Tolerated Functional Groups: Ethers R–O–R, R–S–R, Imines RN=CHR. Amides, primary and secondary amines, carbamates are not stable to the reaction condition An asymmetric version of this reaction is also known with a TADDOL-based catalyst.

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Numerology

  1. Chaldean Numerology

    The numerical value of kulinkovich reaction in Chaldean Numerology is: 6

  2. Pythagorean Numerology

    The numerical value of kulinkovich reaction in Pythagorean Numerology is: 4

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"kulinkovich reaction." Definitions.net. STANDS4 LLC, 2024. Web. 13 Nov. 2024. <https://www.definitions.net/definition/kulinkovich+reaction>.

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